Lithium Enables Pd-Catalyzed 5

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
19 Sep 2024
Historique:
medline: 20 9 2024
pubmed: 20 9 2024
entrez: 19 9 2024
Statut: aheadofprint

Résumé

Tight chelation of enolate by lithium alters the selectivity of tandem palladium-catalyzed cyclization/coupling of terminal α-homopropargyl-β-ketoesters with aryl halides. In the presence of LiOH, substituted cyclopentenes are preferentially formed via 5-

Identifiants

DOI: 10.1021/acs.orglett.4c02846 PMID: 39298715
pubmed: 39298715
doi: 10.1021/acs.orglett.4c02846
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Auteurs

Bartosz Bisek (B)

Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
ORCID: 0000-0003-2020-6068

Katarzyna Kochaniak (K)

Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.

Wojciech Chaładaj (W)

Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
ORCID: 0000-0001-8143-3788

Classifications MeSH