Competing Mechanisms in Palladium-Catalyzed Alkoxycarbonylation of Styrene.
Journal
ACS catalysis
ISSN: 2155-5435
Titre abrégé: ACS Catal
Pays: United States
ID NLM: 101562209
Informations de publication
Date de publication:
19 Apr 2024
19 Apr 2024
Historique:
received:
12
02
2024
revised:
18
03
2024
accepted:
18
03
2024
medline:
25
4
2024
pubmed:
25
4
2024
entrez:
25
4
2024
Statut:
epublish
Résumé
Palladium-catalyzed carbonylation is a versatile method for the synthesis of various aldehydes, esters, lactones, or lactams. Alkoxycarbonylation of alkenes with carbon monoxide and alcohol produces either saturated or unsaturated esters as a result of two distinct catalytic cycles. The existing literature presents an inconsistent account of the procedures favoring oxidative carbonylation products. In this study, we have monitored the intermediates featured in both catalytic cycles of the methoxycarbonylation of styrene PhCH=CH
Identifiants
pubmed: 38660606
doi: 10.1021/acscatal.4c00966
pmc: PMC11036401
doi:
Types de publication
Journal Article
Langues
eng
Pagination
5710-5719Informations de copyright
© 2024 The Authors. Published by American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.