Concentration-dependent Cycling of Phenothiazine-based Electrolytes in Nonaqueous Redox Flow Cells.
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
01 Mar 2023
01 Mar 2023
Historique:
revised:
10
01
2023
received:
18
11
2022
pubmed:
13
1
2023
medline:
13
1
2023
entrez:
12
1
2023
Statut:
ppublish
Résumé
Increasing redox-active species concentrations can improve viability for organic redox flow batteries by enabling higher energy densities, but the required concentrated solutions can become viscous and less conductive, leading to inefficient electrochemical cycling and low material utilization at higher current densities. To better understand these tradeoffs in a model system, we study a highly soluble and stable redox-active couple, N-(2-(2-methoxyethoxy)ethyl)phenothiazine (MEEPT), and its bis(trifluoromethanesulfonyl)imide radical cation salt (MEEPT-TFSI). We measure the physicochemical properties of electrolytes containing 0.2-1 M active species and connect these to symmetric cell cycling behavior, achieving robust cycling performance. Specifically, for a 1 M electrolyte concentration, we demonstrate 94% materials utilization, 89% capacity retention, and 99.8% average coulombic efficiency over 435 h (100 full cycles). This demonstration helps to establish potential for high-performing, concentrated nonaqueous electrolytes and highlights possible failure modes in such systems.
Identifiants
pubmed: 36632659
doi: 10.1002/asia.202201171
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201171Subventions
Organisme : Joint Center for Energy Storage Research (JCESR)
Organisme : National Science Foundation (NSF)
ID : 2141064
Informations de copyright
© 2023 Wiley-VCH GmbH.
Références
L. Trahey, F. R. Brushett, N. P. Balsara, G. Cedera, L. Cheng, Y.-M. Chiang, N. T. Hahn, B. J. Ingram, S. D. Minteer, J. S. Moore, K. T. Mueller, L. F. Nazar, K. A. Persson, D. J. Siegel, K. Xu, K. R. Zavadil, V. Srinivasan, G. W. Crabtree, Proc. Nat. Acad. Sci. 2020, 117, 12550-12557.
M. Li, Z. Rhodes, J. R. Cabrera-Pardo, S. D. Minteer, Sustain. Energy Fuels 2020, 4, 4370-4389.
K. Wedege, E. Dražević, D. Konya, A. Bentien, Sci. Rep. 2016, 6, 39101.
P. Leung, A. Shah, L. Sanz, C. Flox, J. Morante, Q. Xu, M. Mohamed, C. P. de Lěn, F. Walsh, J. Power Sources 2017, 360, 243-283.
X. Wei, W. Pan, W. Duan, A. Hollas, Z. Yang, B. Li, Z. Nie, J. Liu, D. Reed, W. Wang, V. Sprenkle, ACS Energy Lett. 2017, 2, 2187-2204.
Z. Li, T. Jiang, M. Ali, C. Wu, W. Chen, Energy Storage Mater. 2022, 50, 105-138.
Y. Yan, S. G. Robinson, M. S. Sigman, M. S. Sanford, J. Am. Chem. Soc. 2019, 141, 15301-15306.
A. M. Fenton, R. K. Jha, B. J. Neyhouse, A. P. Kaur, D. A. Dailey, S. A. Odom, F. R. Brushett, J. Mater. Chem. A 2022, 10, 17988-17999.
A. P. Kaur, N. E. Holubowitch, S. Ergun, C. F. Elliott, S. A. Odom, Energy Technol. 2015, 3, 476-480.
J. D. Milshtein, A. P. Kaur, M. D. Casselman, J. A. Kowalski, S. Modekrutti, P. L. Zhang, N. H. Attanayake, C. F. Elliott, S. R. Parkin, C. Risko, F. R. Brushett, S. A. Odom, Energy Environ. Sci. 2016, 9, 3531-3543.
N. H. Attanayake, Z. Liang, Y. Wang, A. P. Kaur, S. R. Parkin, J. K. Mobley, R. H. Ewoldt, J. Landon, S. A. Odom, Mater Adv 2021, 2, 1390-1401.
Y. Zhao, E. S. Sarnello, L. A. Robertson, J. Zhang, Z. Shi, Z. Yu, S. R. Bheemireddy, Y. Z, T. Li, R. S. Assary, L. Cheng, Z. Zhang, L. Zhang, I. A. Shkrob, J. Phys. Chem. B 2020, 124, 10409-10418.
S. G. Robinson, Y. Yan, K. H. Hendriks, M. S. Sanford, M. S. Sigman, J. Am. Chem. Soc. 2019, 141, 10171-10176.
K. Takechi, Y. Kato, Y. Hase, Adv. Mater. 2015, 27, 2501-2506.
G. Kwon, K. Lee, M. H. Lee, B. Lee, S. Lee, S.-K. Jung, K. Ku, J. Kim, S. Y. Park, J. E. Kwon, Chem 2019, 5, 2642-2656.
P. Geysens, Y. Li, I. Vankelecom, J. Fransaer, K. Binnemans, ACS Sustainable Chem. Eng. 2020, 8, 3832-3843.
E. Romadina, I. Volodin, K. Stevenson, P. Troshin, J. Mater. Chem. A 2021, 9, 8303-8307.
J. Chai, A. Lashgari, Z. Cao, C. K. Williams, X. Wang, J. Dong, J. J. Jiang, ACS Appl. Mater. Interfaces 2020, 12, 15262-15270.
N. H. Attanayake, J. A. Kowalski, K. Greco, M. D. Casselman, J. D. Milshtein, S. J. Chapman, S. R. Parkin, F. R. Brushett, S. A. Odom, Chem. Mater. 2019, 31, 4353-4363.
J. Huang, L. Cheng, R. S. Assary, P. Wang, Z. Xue, A. K. Burrell, L. A. Curtiss, L. Zhang, Adv. Energy Mater. 2015, 5, 1401782-1401788.
M. Li, S. A. Odom, A. R. Pancoast, L. A. Robertson, T. P. Vaid, G. Agarwal, H. A. Doan, Y. Wang, T. M. Suduwella, S. R. Bheemireddy, R. H. Ewoldt, R. S. Assary, L. Zhang, M. S. Sigman, S. D. Minteer, ACS Energy Lett. 2021, 6, 3932-3943.
J. Zhang, R. Corman, J. K. Schuh, R. H. Ewoldt, I. A. Shkrob, L. Zhang, J. Phys. Chem. C 2018, 122, 8159-8172.
L. A. Robertson, Z. Li, Y. Cao, I. A. Shkrob, M. Tyagi, K. C. Smith, L. Zhang, J. S. Moore, J. Am. Chem. Soc. 2019, 141, 8041-8046.
I. A. Shkrob, T. Li, E. Sarnello, L. A. Robertson, Y. Zhao, H. Farag, Z. Yu, J. Zhang, S. R. Bheemireddy, Y. Z, R. S. Assary, R. H. Ewoldt, L. Cheng, L. Zhang, J. Phys. Chem. B 2020, 124, 10226-10236.
I. A. Shkrob, L. A. Robertson, Z. Yu, R. S. Assary, L. Cheng, L. Zhang, E. Sarnello, X. Liu, T. Li, A. P. Kaur, T. M. Suduwella, S. A. Odom, Y. Wang, R. H. Ewoldt, H. M. Farag, Y. Z, J. Mol. Liq. 2021, 334, 116533.
Y. Wang, A. P. Kaur, N. H. Attanayake, Z. Yu, T. M. Suduwella, L. Cheng, S. A. Odom, R. H. Ewoldt, Phys. Fluids 2020, 32, 083108.
T. J. Carney, S. J. Collins, J. S. Moore, F. R. Brushett, Chem. Mater. 2017, 29, 4801-4810.
R. Darling, K. G. Gallagher, J. A. Kowalski, S. Ha, F. R. Brushett, Energy Environ. Sci. 2014, 7, 3459-3477.
R. Darling, K. Gallagher, W. Xie, L. Su, F. Brushett, J. Electrochem. Soc. 2016, 163, A5029-A5040.
W. Duan, J. Huang, J. A. Kowalski, I. A. Shkrob, M. Vijayakumar, E. Walter, B. Pan, Z. Yang, J. D. Milshtein, B. Li, C. Liao, Z. Zhang, W. Wang, J. Liu, J. S. Moore, F. R. Brushett, L. Zhang, X. Wei, ACS Energy Lett. 2017, 2, 1156-1161.
Z. Liang, N. H. Attanayake, K. V. Greco, B. J. Neyhouse, J. L. Barton, A. P. Kaur, W. L. Eubanks, F. R. Brushett, J. Landon, S. A. Odom, ACS Appl. Energ. Mater. 2021, 4, 5443-5451.
A. M. Kosswattaarachchi, T. R. Cook, Electrochim. Acta 2018, 261, 296-306.
A. P. Kaur, O. C. Harris, N. H. Attanayake, Z. Liang, S. R. Parkin, M. H. Tang, S. A. Odom, Chem. Mater. 2020, 32, 3007-3017.
B. Hu, T. L. Liu, J. Energy Chem. 2018, 27, 1326-1322.