A Crystalline 1D Dynamic Covalent Polymer.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
31 Aug 2022
31 Aug 2022
Historique:
pubmed:
23
8
2022
medline:
23
8
2022
entrez:
22
8
2022
Statut:
ppublish
Résumé
The synthesis of crystalline one-dimensional polymers provides a fundamental understanding about the structure-property relationship in polymeric materials and allows the preparation of materials with enhanced thermal, mechanical, and conducting properties. However, the synthesis of crystalline one-dimensional polymers remains a challenge because polymers tend to adopt amorphous or semicrystalline phases. Herein, we report the synthesis of a crystalline one-dimensional polymer in solution by dynamic covalent chemistry. The structure of the polymer has been unambiguously confirmed by microcrystal electron diffraction that together with charge transport studies and theoretical calculations show how the π-stacked chains of the polymer generate optimal channels for charge transport.
Identifiants
pubmed: 35993775
doi: 10.1021/jacs.2c06446
pmc: PMC9446889
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
15443-15450Subventions
Organisme : NIGMS NIH HHS
ID : R21 GM135784
Pays : United States
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