Metal-Free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes.
Frustrated Lewis Pair
H2 Activation
Hydrogenolysis
Hydrosilane Synthesis
Metal-Free
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
07 Jun 2022
07 Jun 2022
Historique:
received:
18
01
2022
pubmed:
23
3
2022
medline:
23
3
2022
entrez:
22
3
2022
Statut:
ppublish
Résumé
The metal-free catalytic hydrogenolysis of silyl triflates and halides (I, Br) to hydrosilanes is unlocked by using arylborane Lewis acids as catalysts. In the presence of a nitrogen base, the catalyst acts as a Frustrated Lewis Pair (FLP) able to split H
Identifiants
pubmed: 35315969
doi: 10.1002/anie.202200911
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202200911Subventions
Organisme : CINES (HPC Computing time in Occigen)
ID : A0100806494
Organisme : European Research Council
ID : 818260
Pays : International
Commentaires et corrections
Type : ErratumIn
Informations de copyright
© 2022 Wiley-VCH GmbH.
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