Filming ultrafast roaming-mediated isomerization of bismuth triiodide in solution.
Journal
Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555
Informations de publication
Date de publication:
05 Aug 2021
05 Aug 2021
Historique:
received:
13
04
2021
accepted:
20
07
2021
entrez:
6
8
2021
pubmed:
7
8
2021
medline:
7
8
2021
Statut:
epublish
Résumé
Roaming reaction, defined as a reaction yielding products via reorientational motion in the long-range region (3 - 8 Å) of the potential, is a relatively recently proposed reaction pathway and is now regarded as a universal mechanism that can explain the unimolecular dissociation and isomerization of various molecules. The structural movements of the partially dissociated fragments originating from the frustrated bond fission at the onset of roaming, however, have been explored mostly via theoretical simulations and rarely observed experimentally. Here, we report an investigation of the structural dynamics during a roaming-mediated isomerization reaction of bismuth triiodide (BiI
Identifiants
pubmed: 34354075
doi: 10.1038/s41467-021-25070-z
pii: 10.1038/s41467-021-25070-z
pmc: PMC8342516
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4732Informations de copyright
© 2021. The Author(s).
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