Catalytic Oxygenation of Hydrocarbons by Mono-μ-oxo Dicopper(II) Species Resulting from O-O Cleavage of Tetranuclear Cu
Raman spectroscopy
catalysis
copper
metalloenzymes
oxygenation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
14 06 2021
14 06 2021
Historique:
revised:
13
04
2021
received:
22
01
2021
pubmed:
16
4
2021
medline:
16
4
2021
entrez:
15
4
2021
Statut:
ppublish
Résumé
One of the challenges of catalysis is the transformation of inert C-H bonds to useful products. Copper-containing monooxygenases play an important role in this regard. Here we show that low-temperature oxygenation of dinuclear copper(I) complexes leads to unusual tetranuclear, mixed-valent μ
Identifiants
pubmed: 33856088
doi: 10.1002/anie.202101035
pmc: PMC8251984
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
14154-14162Informations de copyright
© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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