CuCl
arylation
halogenation
ketones
quaternary stereocenters
umpolung
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
16 Nov 2020
16 Nov 2020
Historique:
received:
07
08
2020
revised:
01
10
2020
pubmed:
8
10
2020
medline:
8
10
2020
entrez:
7
10
2020
Statut:
ppublish
Résumé
α-Functionalization of ketones in an umpolung fashion can be achieved by nucleophilic addition to the oxy-allyl cation intermediate. However, applicable carbon nucleophiles are limited to ones with high nucleophilicity. Additionally, introduction of a leaving group to the α-position of ketone substrates is required beforehand. Herein, we report the CuCl
Identifiants
pubmed: 33025747
doi: 10.1002/asia.202001032
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3816-3819Subventions
Organisme : JSPS KAKENHI Grant
ID : JP26220803
Organisme : JSPS KAKENHI Grant
ID : JP18H01975
Organisme : JSPS KAKENHI Grant
ID : JP20H04815
Informations de copyright
© 2020 Wiley-VCH GmbH.
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Since N,N-dimethylaniline was smoothly consumed in the presence of CuCl2, it seems to be difficult to apply the present method to the substrate having a nitrogen tether instead of the oxygen linkage.