Hysteresis in the gas sorption isotherms of metal-organic cages accompanied by subtle changes in molecular packing.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
26 Mar 2020
26 Mar 2020
Historique:
pubmed:
4
3
2020
medline:
4
3
2020
entrez:
4
3
2020
Statut:
ppublish
Résumé
Structural deformation in response to gas sorption is rarely observed for porous molecular solids, when compared to porous framework materials. Here, we describe the effect of chemical modification on the exterior of lantern-type metal-organic cages on the emergence and then disappearance of cooperative gas uptake. The results suggest that supramolecular design of ligands can be used to reveal this behaviour.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM