Visible-Light-Induced Metal-/Photocatalyst-Free C-H Bond Imidation of Arenes.
Journal
Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393
Informations de publication
Date de publication:
20 Mar 2020
20 Mar 2020
Historique:
pubmed:
3
3
2020
medline:
3
3
2020
entrez:
3
3
2020
Statut:
ppublish
Résumé
In this study, a visible-light-induced intermolecular C-H bond imidation of arenes was achieved at ambient condition. By using simple phthalimide with (diacetoxyiodo)benzene and molecular iodine, direct metal-/photocatalyst-free C-N bond formation was achieved. The imidation protocol was designed by using time-dependent density functional theory calculations and experimentally demonstrated for 28 substrates with as high as 96% yield. Mechanistic studies indicated that radical-mediated aromatic substitution occurred via photolysis of
Identifiants
pubmed: 32119559
doi: 10.1021/acs.orglett.0c00433
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM