Expanding the BN-embedded PAH family: 4a-aza-12a-borachrysene.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
28 Mar 2020
28 Mar 2020
Historique:
pubmed:
3
3
2020
medline:
3
3
2020
entrez:
3
3
2020
Statut:
ppublish
Résumé
Previously unknown 4a-aza-12a-borachrysene has been synthesized in only four steps. The reactions of this BN-embedded PAH with bromine and organolithium compounds proceed with complete regioselectivity, resulting in the formation of nine derivatives. One of these, a phenylalkynyl-substituted derivative, exhibits a remarkably high fluorescence quantum yield (Φ
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM