Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism).
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
19 Nov 2019
19 Nov 2019
Historique:
pubmed:
7
11
2019
medline:
7
11
2019
entrez:
6
11
2019
Statut:
ppublish
Résumé
The hunt for high-performance single-molecule magnets (SMM) revealed that atomic and molecular lanthanide systems combining 4f-shell and valence magnetism (FV-magnetism) may show magnetic bistability up to unexpectedly high temperatures. Here we rationalize the stability of the magnetism in the FV-systems from first principles on the example of LnII(CpiPr5)2 molecules.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM