Stepwise Evolution of Molecular Nanoaggregates Inside the Pores of a Highly Flexible Metal-Organic Framework.

crystalline sponge method eugenol metal-organic frameworks nanoaggregates solvent-to-guest exchange

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
25 Nov 2019
Historique:
received: 19 06 2019
revised: 30 08 2019
pubmed: 25 9 2019
medline: 25 9 2019
entrez: 25 9 2019
Statut: ppublish

Résumé

The crystalline sponge method (CSM) is primarily used for structural determination by single-crystal X-ray diffraction of a single analyte encapsulated inside a porous MOF. As the host-guest systems often show severe disorder, reliable crystallographic determination is demanding; thus the dynamics of the guest entering and the formation of nanoconfined molecular aggregates has not been in the spotlight. Now, the concept is investigated of the CSM for monitoring the structural evolution of nanoconfined supramolecular aggregates of eugenol guests with displacement of DMF inside the cavities of the flexible MOF, PUM168. The interpretation of the electron density provides a series of unique detailed snapshots depicting the supramolecular guest aggregation, thus showing the tight interplay between the host flexible skeleton and the molecular guests through the DMF-to-eugenol exchange process.

Identifiants

pubmed: 31549464
doi: 10.1002/anie.201907621
doi:

Types de publication

Journal Article Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

17342-17350

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Davide Balestri (D)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale delle Scienze, 17A, 43124, Parma, Italy.

Paolo P Mazzeo (PP)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale delle Scienze, 17A, 43124, Parma, Italy.
Biopharmanet-TEC, Università degli studi di Parma, via Parco Area delle Scienze 27/A, 43124, Parma, Italy.

Claudia Carraro (C)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale delle Scienze, 17A, 43124, Parma, Italy.

Nicola Demitri (N)

Elettra-Sincrotrone Trieste, S.S. 14 Km 163.5 in Area Science Park, 34149 Basovizza-, Trieste, Italy.

Paolo Pelagatti (P)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale delle Scienze, 17A, 43124, Parma, Italy.
Centro Interuniveristario di Reattività Chimica e Catalisi (CIRCC), Via Celso Ulpiani 27, 70126, Bari, Italy.

Alessia Bacchi (A)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale delle Scienze, 17A, 43124, Parma, Italy.
Biopharmanet-TEC, Università degli studi di Parma, via Parco Area delle Scienze 27/A, 43124, Parma, Italy.

Classifications MeSH