Photophysical Properties of Upconverting Nanoparticle-Phthalocyanine Complexes.


Journal

Biochemistry. Biokhimiia
ISSN: 1608-3040
Titre abrégé: Biochemistry (Mosc)
Pays: United States
ID NLM: 0376536

Informations de publication

Date de publication:
Aug 2019
Historique:
entrez: 17 9 2019
pubmed: 17 9 2019
medline: 18 12 2019
Statut: ppublish

Résumé

Interaction between upconverting nanoparticles and aluminum octacarboxyphthalocyanine was studied. The efficiency of non-radiative energy transfer from the nanoparticles to phthalocyanine increased with the number of phthalocyanine molecules adsorbed on the nanoparticle, but only up to a certain limit. Further increase in the phthalocyanine concentration resulted in a decrease of its sensitized fluorescence due to the dimerization of dye molecules on the nanoparticle surface. When subjected to infrared irradiation, phthalocyanine molecules in the hybrid complex generated singlet oxygen. The observed effects are of interest in regard to the targeted search for new components of efficient third-generation hybrid photosensitizers.

Identifiants

pubmed: 31522673
pii: BCM84081154
doi: 10.1134/S0006297919080078
doi:

Substances chimiques

Indoles 0
Isoindoles 0
Organometallic Compounds 0
Photosensitizing Agents 0
Singlet Oxygen 17778-80-2
aluminum phthalocyanine 47822-79-7
phthalocyanine V5PUF4VLGY

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

911-922

Auteurs

D A Gvozdev (DA)

Lomonosov Moscow State University, Faculty of Biology, Moscow, 119991, Russia. danil131054@mail.ru.

E P Lukashev (EP)

Lomonosov Moscow State University, Faculty of Biology, Moscow, 119991, Russia.

V V Gorokhov (VV)

Lomonosov Moscow State University, Faculty of Biology, Moscow, 119991, Russia.

V Z Pashchenko (VZ)

Lomonosov Moscow State University, Faculty of Biology, Moscow, 119991, Russia.

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Classifications MeSH