A novel method for the preconcentration and determination of ampicillin using electromembrane microextraction followed by high-performance liquid chromatography.
ampicillin
cow milk
electromembrane extraction
high performance liquid chromatography
reduced graphene oxide
Journal
Journal of separation science
ISSN: 1615-9314
Titre abrégé: J Sep Sci
Pays: Germany
ID NLM: 101088554
Informations de publication
Date de publication:
Sep 2019
Sep 2019
Historique:
received:
08
01
2019
revised:
30
06
2019
accepted:
30
06
2019
pubmed:
12
7
2019
medline:
11
3
2020
entrez:
12
7
2019
Statut:
ppublish
Résumé
Electromembrane extraction was used with high-performance liquid chromatography for preconcentration and determination of ampicillin residues in cow milk. Ampicillin is transferred from an aqueous solution through a thin layer containing octan-1-ol, silver nanoparticles, and reduced graphene oxide which serves as a supported liquid membrane. Inside the fiber impregnated with supported liquid membrane mixture was filled 10 µL of an acceptor phase. Experimental parameters were optimized for extraction efficiency of ampicillin. Under the optimized conditions, the proposed method provided acceptable linear range (2-100 µg/L), satisfactory repeatability (RSD% < 7.1), low limit of detection (0.6 µg/L), and a high enrichment factor (295) corresponding to extraction recovery of 37%. Consequently, the proposed method was successfully applied for the determination of ampicillin residues in different cow milks.
Identifiants
pubmed: 31294510
doi: 10.1002/jssc.201900016
doi:
Substances chimiques
Silver
3M4G523W1G
Ampicillin
7C782967RD
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3002-3008Informations de copyright
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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