Luminescent mechanochromism of gold N-heterocyclic carbene complexes with hypso- and bathochromic spectral shifts.

Journal

Dalton transactions (Cambridge, England : 2003)
ISSN: 1477-9234
Titre abrégé: Dalton Trans
Pays: England
ID NLM: 101176026

Informations de publication

Date de publication:
07 Jun 2019
Historique:
pubmed: 27 3 2019
medline: 27 3 2019
entrez: 27 3 2019
Statut: ppublish

Résumé

Two gold N-heterocyclic carbene complexes show contrasting luminescent mechanochromism behavior with hypso- and bathochromic spectral shifts. The distinct emission shifts upon mechanical stimulation can be explained by the aggregate-to-monomer transformation and intensified intermolecular interactions, respectively.

Identifiants

DOI: 10.1039/c9dt00566h PMID: 30912793
pubmed: 30912793
doi: 10.1039/c9dt00566h
doi:

Types de publication

Journal Article

Langues

eng

Pagination

7105-7109

Auteurs

Tomohiro Seki (T)

Division of Applied Chemistry & Frontier Chemistry Center, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan. seki@eng.hokudai.ac.jp hajito@eng.hokudai.ac.jp.
ORCID: 0000-0002-4642-1324

Kentaro Kashiyama (K)

Division of Applied Chemistry & Frontier Chemistry Center, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan. seki@eng.hokudai.ac.jp hajito@eng.hokudai.ac.jp.

Hajime Ito (H)

Division of Applied Chemistry & Frontier Chemistry Center, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan. seki@eng.hokudai.ac.jp hajito@eng.hokudai.ac.jp and Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University 060-8628, Japan.
ORCID: 0000-0003-3852-6721

Classifications MeSH