Imine hydrosilylation using an iron complex catalyst: A computational study.
DFT
hydrosilane
hydrosilylation of imine
iron complex catalyst
reaction mechanism
Journal
Journal of computational chemistry
ISSN: 1096-987X
Titre abrégé: J Comput Chem
Pays: United States
ID NLM: 9878362
Informations de publication
Date de publication:
05 Jan 2019
05 Jan 2019
Historique:
received:
15
05
2018
revised:
26
06
2018
accepted:
26
06
2018
pubmed:
24
10
2018
medline:
24
10
2018
entrez:
24
10
2018
Statut:
ppublish
Résumé
The reaction mechanism for imine hydrosilylation in the presence of an iron methyl complex and hydrosilane was studied using density functional theory at the M06/6-311G(d,p) level of theory. Benzylidenemethylamine (PhCH = NMe) and trimethylhydrosilane (HSiMe
Types de publication
Journal Article
Langues
eng
Pagination
62-71Subventions
Organisme : DAIKO FOUNDATION
ID : 10142
Organisme : JST-CREST
ID : JPMJCR13L5
Informations de copyright
© 2018 Wiley Periodicals, Inc.