Steric Demand and Rate-determining Step for Photoenolization of Di-ortho-substituted Acetophenone Derivatives.

Journal

Photochemistry and photobiology
ISSN: 1751-1097
Titre abrégé: Photochem Photobiol
Pays: United States
ID NLM: 0376425

Informations de publication

Date de publication:
01 2019
Historique:
received: 26 05 2018
accepted: 01 08 2018
pubmed: 14 8 2018
medline: 14 8 2018
entrez: 14 8 2018
Statut: ppublish

Résumé

Laser flash photolysis of ketone 1 in argon-saturated methanol yields triplet biradical 1BR (τ = 63 ns) that intersystem crosses to form photoenols Z-1P (λ

Identifiants

DOI: 10.1111/php.12996 PMID: 30103294
pubmed: 30103294
doi: 10.1111/php.12996
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Pagination

154-162

Subventions

Organisme : National Science Foundation
ID : CHE-1464694
Pays : International
Organisme : Ohio Supercomputer Center
ID : PES0597
Pays : International
Organisme : NSERC
ID : RGPIN-121389-2012
Pays : International
Organisme : CAMTEC
Pays : International

Informations de copyright

© 2018 The American Society of Photobiology.

Auteurs

Anushree Das (A)

Department of Chemistry, University of Cincinnati, Cincinnati, OH.

Suma S Thomas (SS)

Department of Chemistry and Centre for Advanced Materials and Related Technologies (CAMTEC), University of Victoria, Victoria, BC, Canada.

August A Garofoli (AA)

Department of Chemistry, University of Cincinnati, Cincinnati, OH.

Kevin A Chavez (KA)

Department of Chemistry, University of Cincinnati, Cincinnati, OH.

Jeanette A Krause (JA)

Department of Chemistry, University of Cincinnati, Cincinnati, OH.

Cornelia Bohne (C)

Department of Chemistry and Centre for Advanced Materials and Related Technologies (CAMTEC), University of Victoria, Victoria, BC, Canada.

Anna D Gudmundsdottir (AD)

Department of Chemistry, University of Cincinnati, Cincinnati, OH.

Classifications MeSH